Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. The main concept is the combination of noncatalytic partial oxidation and adiabatic catalytic steam reforming. Design and control of the dry methane reforming process. A may 2019 paper published in science reports on a technological advance that may have significant implications for ammonia production. Under these conditions, the catalyst presents the average h2co. Design of process plant for producing hydrogen from steam. Integration of methane steam reforming and water gas shift reaction in a pdaupdbased catalytic membrane reactor for process intensi. A good catalyst design will have a low pressure drop to save on operating costs and have a high conversion. Membrane reactor, steam reforming, mathematical model. The long microchannel finned reactor design mitigates the potential for.
Steam reacts with natural gas, producing hydrogen and carbon monoxide. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. The steam methane reforming process can be broken down into five distinct steps. Also, the process description of steam methane reforming smr with flow sheet was discussed. The present cfd model showed a potential for the development of new design of the smr reactor.
Steam reforming of natural gas at petroleum refining facilities is the. Steam reforming of methane for production of hydrogen and methanol. The first cooling step is followed by the hightemperature shift reactor, and the. Steam methane reforming smr is a major hydrogen production process with more than 70 years of history.
Subsequently the modeling of the chemical reactions in, and of the heat transfer to the reactor tubes, will be discussed in section 3. Steam reforming of natural gas the most economical and highly preferable process with the resources of eritrea is steam reforming of natural gas. Methane steam reforming reaction behaviour in a packed. In the water shift reactor, carbon monoxide and steam react to form carbon dioxide and more hydrogen gas. Pdf on the modeling of steam methane reforming researchgate.
The steammethane reforming over rhodium coupled with methane. The partial pressures of ch4 and h2o were varied between 20 and 140 kpa and 80 and 320 kpa, resp. This is achieved in a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. The models included all the feed pretreatment steps along with the reforming reactors and effluent treatment.
The fixed bed reactor is filled with a nickel oxide catalyst. In smr, methane reacts with steam under 325 bar pressure 1 bar 14. Comparison of catalyst geometries for methane steam. The two main reformers, the steam methane reformer smr and the autothermal reformer atr were modelled.
Improving downfired steam methane reforming flue gas. Progresses in the preparation of coke resistant ni. I am required to design a steam reformer alongside a furnace for a design project. Prereforming works as an adiabatic steam reforming step over a ni based catalyst. The main purpose of this technology is hydrogen production. Higher reactor pressures reduce compression costs of the synthesis gas. A simulation study of the steam reforming of methaneina. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. This reactor gave 95% conversion of methane to synthesis gas with a residence time of. This process contains two chemical reactions which ultimately convert water and methane usually in the form of. Methane steam reforming methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. These tunnels range from 4 to 10 feet high, 2 to 3 feet wide, and 40 to 100 feet long, depending on the unit design capacity.
Effects of operating conditions such as temperature and steam to methane ratio on the reformer performance are investigated. Meanwhile, the steam methane reformer refers only to the fired chemical reactor in which reaction takes place. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. An experimental and modelling study of the pyrolysis and of the steam reforming of methane in mixtures representative of a gas produced from biomass gasification has been performed. Soliman chemical reaction engineering group creg chemical engineering department, col lege o f engineering king saud u n. The experimental study has been done in a plug flow reactor under a near atmospheric pressure 1. A conventional steam reformer unit consists of several hundred fixedbed reactor tubes filled with a.
This physical modeling will be used in a lumped parameter model of the steady state operation of the reactor. Steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. This name is commonly retained even when other feedstocks e. The present compact type smr reactor showed a flatter heat flux profile than conventional reactor designs in literatures. The literature relating to the kinetics of methanesteam reforming involving integral and differential reactor data, porous nickel catalysts and nickel foil, and data over large ranges of temperature 500 to 1700sup 0f, pressure 0. Measurements were carried out without mass and heat transport limitations, as verified by the weisz. Catalyst design influences process variables such as pressure drop, conversion, and heat transfer. The methane steam reforming reaction has been investigated from a modeling point of view, considering the effect of different parameters on methane conversion. Simulation results show that the steam reforming of methane in a fixedbed reactor can efficiently store high temperature end thermal energy. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted. Methane steam reforming consists in the reaction of methane and steam on a supported nickel catalyst to produce a mixture of h 2, co, co 2 and ch 4. First in section 2 the design of a tubular reforming reactor will be explained. A modelling and experimental approach article in international journal of hydrogen energy january 2015 with 173 reads how we measure reads. Steam methane reforming is the most common and economical way to make hydrogen.
Methane steam reforming an overview sciencedirect topics. The reformer furnace design alternatives will be discussed below. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas. A parallel plate catalytic wall reactor was built in which exothermic methane combustion on platinum and endothermic methane steam reforming on rhodium occurred on walls in alternate channels. The design of the steam reforming process is in part dictated by these constraints. The equilibrium composition out of the steam reformer is shown in fig.
The basis for the reforming may be considered as the reaction between a. Hydrogen from natural gas via steam methane reforming smr. Yurchak editors, methane conversion 0 1988 elsevier science publishers b. High levels of purity can be reached by employing inhouse pressure swing adsorption purification technology. The thermochemical watersplitting process offers a novel means for largescale.
Catalytic reforming of methane in the presence of co2. The steam methane reforming smr reaction was studied on a nimgosio2 catalyst at 923 k 650 c and 0. For decades, downfired steam methane reformer furnaces have utilized flue gas tunnels aka coffins along the radiant section floor to collect and improve flue gas flow uniformity. Advanced modelling and optimisation of natural gas. Journals az books and reference advertising media kit. A compact approach to greener industrial hydrogen production, presents a method for providing the heat required for steam methane reforming from renewable electricity instead of. Pdf modeling and simulations of steam methane reforming smr process to produce hydrogen. As the temperature is increased, the hydrogen yield increases, which is observed as a reduction in the methane concentration in the reformer effluent, known as. Heat and mass transfer correlations for steam methane reforming.
Technoeconomic study of hydrogen production via steam. This thesis considers the design and operational feasibility of heat integrating two conventional industrial processes gasification and steam reforming of methane for application in polygeneration. Electrified methane reforming could reduce ammonias co2. Autothermal reforming an overview sciencedirect topics. Steam reforming of methane in a synthesis gas from biomass. Carbon deposition in steam reforming and methanation. Kinetics study and modelling of steam methane reforming. Consequently, the yield of hydrogen depends in a complex manner upon the design.
Co are also active for the methane steam reforming 25. This keeps the production costs off the books from the adjacent user and has found. An industrial steam reforming reactor producing hydrogen is simulated using the threedimensional computational fluid dynamics cfd technique. The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst. Currently, this process is the main route to obtain hydrogen and synthesis gas for ammonia and methanol. Structure sensitivity in steam and dry methane reforming. Water enters the furnace, producing steam at a very high temperature.
To this end, complex mathematical models that describe the integrated system are developed to study different design prospects and to determine. Design and evaluation of heat utilization systems for. The various hydrogen production schemes were investigated for three different fuels. Hydrogen production by steam reforming chemical engineering.
However, higher pressures also require a higher reactor temperature to achieve high methane conversion. Kinetics, catalysis and mechanism of methane steam reforming. Both methane conversion and hydrogen recovery are higher in. To react hydrocarbon feed with steam to give a methane rich product suitable for further downstream reforming. Cuoznoal 2 o 3 is used as the catalyst for the msr while the required heat is provided using platinum pt. It is highly desired to design and synthesize a coke resistant. The methane steamreforming reaction has been investigated from a modeling point of view, considering the effect of different parameters on methane conversion.
Steam methane reforming smr is the most widely utilized technology for producing hydrogen and synthesis gas from natural gas feedstocks. Autothermal reforming atr is an important industrial process used to produce syngas with a low h2 co ratio from 1. In this project report, the steam reforming is studied and done many research about the various production methods of hydrogen. Methane steam reforming is a wellestablished process as shown in fig. In particular, we point our attention mainly toward the influence of the different retentate and permeate flux configurations on both methane conversion and hydrogen recovery. Over the past 50 years, lummus technology has built more than 200 smr furnaces that produce highpurity gas. Steam methane reforming smr is a chemical process used in the gas manufacturing industry to produce hydrogen on a large scale. Steam reforming or steam methane reforming is a chemical synthesis for producing syngas hydrogen and carbon monoxide from hydrocarbons such as natural gas. The flow disturbance elements designed for the reactor are of great benefit to. Smr is a costeffective and energy efficient way of producing hydrogen.
Design and production of hydrogen gas by steam methane. The dry methane reforming reaction is favored by low pressure, but high pressure synthesis gas is required in the downstream process. Integration of methane steam reforming and water gas shift. Cfd simulation of a methane steam reforming reactor.
A conventional steam reformer unit consists of several hundred fixedbed reactor tubes filled with a catalyst, which can vary in size and geometry. Steam reforming of methane is an extremely important process for the hydrogen and syngas production. The reforming reactions have been investigated from a modelling view point considering the effect of different temperatures ranging from 500. Steam methane reformer an overview sciencedirect topics. Areas where hydrogen is heavily consumed include ammonia production, the cryogenics industry and methanol production table 11. Thus we concentrated more on design of a complete process plant for hydrogen production from steam reforming of natural gas. Compact steammethane reforming for the production of hydrogen. Steam methane reforming hydrogen production air liquide. Steam and hydrocarbon enter the reactor as feedstock, and hydrogen and carbon dioxide are generated at the end of the process. The steam methane reforming reaction is strongly endothermic and is therefore favoured by a higher temperature. The catalyst showed stability and activity at a feed molar ratio sc21, wf 0.